Ceramics-Silikáty 46, (3) 110 - 116 (2002) |
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INFLUENCE OF PORTLAND CEMENT ADDITION TO SULPHOALUMINATE - BELITE CEMENT ON HYDRATION AND MECHANICAL PROPERTIES OF HARDENED MORTARS |
Janotka Ivan 1, Krajči Ľudovit 1, Mojumdar Subhash C. 2 |
1 Institute of Construction and Architecture, Slovak Academy of Sciences
Dubravská cesta 9, Bratislava, Slovak Republic
2 Institute of Inorganic Chemistry, Slovak Academy of Sciences
Dubravská cesta 9, Bratislava, Slovak Republic
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Keywords: Calcium sulphoaluminate-belite cement, Microstructure, Mortar |
Ordinary Portland cement (PC), calcium sulphoaluminate - belite (SAB) cement and a 85 wt. % SAB cement/15 wt.% PC blend
were used for mortar manufacture (cement to sand weight ratio 1 : 3, w/c ratio 0.5) of 40×40×160 mm specimens kept in wet
air cure (20°C, 100 % R.H. for 90 days), and used for the tests. The results reveal the influence of cement type on mortar properties.
The mortars, made from tested SAB cement have the worst mechanical properties. The replacement of 15 wt. % of SAB
cement by PC contributes to the increase in dynamic modulus of elasticity (DME), flexural strength of the mortar by 15 % and
compressive strength almost by 40 % compared to the SAB cement mortar. Such mortar behaves mechanically similar to PC
mortar. Differences in mechanical properties of mortars are caused by differences in chemical composition of cements (in
SAB/PC mortar content of CaO is increased by 6.4 %, contents of Al₂O₃ and Fe₂O₃ are decreased by 8.2 % and 7.0 %, respectively
compared to SAB cement mortar, SO₃ content is 2.6× higher than that in the PC mortar), and mineralogical composition
and hydration kinetics of cements. Differences in mineralogical composition, mainly ettringite formation, and consequently
hydration kinetics are the substantial reason of higher demands on batch water, rapid initial and final set of SAB cement
and lower DME and strength of SAB cement mortar relative to PC and PC mortar, respectively. The 85 wt. % SAB cement/15
wt. % PC blend gains on hydration activity, DME and strength growth by the C₃S activator from PC supporting less-active
SAB cement hydration. Utility properties of SAB/PC mortar are more similar to PC mortar than SAB cement mortar. |
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