Ceramics-Silikáty 46, (2) 41 - 48 (2002) |
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AN ESTIMATE OF ORIENTATION EFFECTS ON THE RESULTS OF SIZE DISTRIBUTION MEASUREMENTS FOR OBLATE PARTICLES |
Pabst Willi, Mikač Jan, Gregorová Eva,
Havrda Jiří |
Department of Glass and Ceramics, Institute of Chemical Technology, Prague
Technická 5, 166 28 Prague, Czech Republic
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Keywords: Particle size distributions, Oblate particles, Laser diffraction |
The influence of the orientation of oblate particles on volume-weighted particle size distributions (PSD) is demonstrated with
an idealized model system. The overall estimate is based on partial "worst case" estimates found by an explicit calculation of
selected non-random orientations for disk-shaped particles with an aspect ratio of 10 and a wide-range PSD. According to
the simulation results the D₁₀, D₅₀ (median) and D₉₀ values for particle orientations of 60°, 45°, 30° and 0° deviate by less than
17 % from those of the 90° orientation (corresponding to projections normal to the disk plane), whereby the maximum deviation
occurs for orientations close to 30°. For quasi-random orientation the deviation is even smaller (approx. 3-7 %). Thus
it is shown that, in contrast to widespread belief, the effect of particle orientation on the resulting volume-weighted PSD is
for oblate particles small enough to be completely smeared out for purely statistical reasons to within typical errors of measurement
of the usual sizing methods. |
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