Ceramics-Silikáty 48, (1) 6 - 13 (2004) |
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FUNDAMENTAL CONSIDERATIONS ON SUSPENSION RHEOLOGY |
Pabst Willi |
Department of Glass and Ceramics, Institute of Chemical Technology Prague,
Technická 5, 166 28 Prague 6, Czech Republic
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Keywords: Suspension rheology, Effective viscosity, Dilute suspensions, Critical volume fraction |
The basic assumptions of suspension rheology (existence of a unique viscosity and dependence of the effective viscosity on
the solids volume fraction) are discussed from the viewpoint of rational mechanics and micromechanics. The most important
effective viscosity formulae are presented in a new way, which clarifies the status of these formulae and makes a clear distinction
between exponential (Mooney-type) relations and power-law (Krieger-type) relations. Based on a functional equation
approach, a tentative explanation is given why the latter are more successful. The Frankel-Acrivos relation is modified
to exhibit correct behavior in the dilute limit. |
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