Ceramics-Silikáty 49, (3) 195 - 204 (2005) |
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GEOPOLYMER MATERIALS BASED ON FLY ASH |
Škvára František 1, Jílek Tomáš 1, Kopecký Lubomír 2 |
1 Department of Glass and Ceramics, Institute of Chemical Technology Prague,
Technická 5, 166 28 Prague, Czech Republic
2 Department of Structural Mechanics, Czech Technical University Prague,
Thákurova 7, 166 29 Prague, Czech Republic
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Keywords: Geopolymer, Fly ash, Durability, Inorganic polymer |
Owing to their high strength and predominantly amorphous microstructure the materials on the basis of latent hydraulic
active substances activated by alkalis (fly ash, slag) represent a transition between traditional inorganic binders and ceramics
and, therefore, they are included into the group of so-called "chemically bonded ceramics". The products being formed
during the alkaline activation of fly ashes exhibit their amorphous character with minority crystalline phases. The materials
prepared on the basis of fly ashes activated by alkalis exhibit an excellent resistance to the corrosive action of salt solutions,
they possess high values of strength and a good frost resistance; furthermore, they can withstand the exposure to temperatures
of up to about 600°C. There is a substantial difference in the corrosion of geopolymer by sulfate solutions and that of
the materials on the basis of Portland cement. |
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