Ceramics-Silikáty 50, (4) 225 - 231 (2006) |
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DENSIFICATION AND GRAIN GROWTH OF SrO-DOPED ZnO |
Güntürkün Kaan, Toplan H. Özkan |
Sakarya University, Metallurgy and Materials Engineering, Sakarya, Turkey
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Keywords: ZnO, Varistor, SrOB Bdoping, Grain growth kinetics, Densification |
The grain growth kinetics in the 1, 2, 3 and 4 wt.% SrO doped ZnO was studied using the simplified phenomenological grain
growth kinetics equation Gn - G0n= K0 t exp(-Q/RT) together with microstructure properties and densification of the sintered
samples. The grain growth exponent values (n) were found to be 5 for 1, 2, 3 and 4 wt.% SrO doped ZnO. The apparent activation
energies for 1, 2, 3 and 4 wt.% SrO doped ZnO were found 780 kJ/mol, 709 kJ/mol, 764 kJ/mol and 744 kJ/mol, respectively.
The apparent activation energy was increased with doping of SrO because of ZnSrO₂ phase at the grain boundaries.
This ZnSrO₂ phase inhibited the grain growth of ZnO. But the increasing SrO level had no effect on the grain growth. Also,
the increasing of SrO resulted in a slight reduction in densification at all temperatures. |
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