Ceramics-Silikáty 53, (3) 211 - 215 (2009) |
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HYDROTHERMAL DEGRADATION OF CERAMIC MATERIALS ON THE NATURAL RAW MATERIALS BASE
Part 1: Physical changes |
Pešová Andrea, Andertová Jana, Gedeon Ondřej |
Department of Glass and Ceramics, Institute of Chemical Technology Prague,
Technicka 5, 16628 Prague, Czech Republic
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Keywords: Clay raw materials, Moisture expansion, Ceramics, Hydrothermal exposure |
The paper deals with simulation of long-lasting atmospheric moisture exposure of ceramic materials on the base of natural
raw materials. The exposure causes the irreversible volume expansion, recorded by as a relative length deformation. Series
of samples from mixtures of clays with dolomite and calcite were prepared and the influence of the changing composition on
the deformation was studied. In the following fired bodies based on kaolinitic clays were exposed to various hydrothermal
conditions, namely two exposure times and two temperatures were used. Correlation between mixtures composition and
length changes (deformation) of material was confirmed. Results have shown a strong dependence of the found irreversible
deformation on the content of kaolinite and hydrothermal exposure conditions. On the other hand, changes of firing regime
didn’t have significant influence on the deformations. |
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