Ceramics-Silikáty 27, (4) 289 - 298 (1983) |
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DIF FUSION OF K+ AND Ag+ IONS INTO SIMAX GLASS FROM MOLTEN SALTS |
Maryška Martin, Matoušek Josef, Hulínský Václav |
Institute of Chemical Technology, Department of the Technology of Silicates, Suchbátarova 5, 166 28 Prague
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Diffusion of Ag+ and K+ ions from AgNO₃ and KNO₃ melts into SIMAX
glass was studied at 335 °C (AgNO₃) and 400-500 °C (KNO₃) using a 6-hour exposure. The concentration profile of silver was determined by the method of gradual etching of layers, and the silver concentration was measured by an ionically selective electrode. The diffusions profiles of potassium were determined by the JXA-5 electron microanalyzer. The diffusion profiles of silver
and potassium were used for calculating the interdiffusion coefficients, and the temperature dependence of D̅Na+/K+ was established. |
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