Ceramics-Silikáty 57 (3) 185-189 (2013)

MONOCLINIC ZIRCONIA SINTERED BODIES PREPARED VIA TWO-STEP SINTERING AND CHARACTERISATION OF SELECTED MECHANICAL PROPERTIES

In the paper we examine some mechanical properties of the unstabilised zirconia sinters, such as Vickers hardness and fracture toughness. The sinters were prepared using two step sintering technique. It is the first time, when two step sintering is used to process unstabilised zirconia nanopowders. As a preparatory experiment, a microstructure evolution of the sinters was determined in order to select the temperatures T₁ and T₂ of two step sintering. The samples were sintered below the monoclinic to tetragonal transformation temperature, using several T₁ and T₂ combinations and different sintering times. The sinters were compared in terms of density, grain size, Vickers' hardness and fracture toughness. The samples were sintered to full density, showing a grain size of 95 nm, Vickers hardness of 11 GPa and fracture toughness of 5.32 MPa∙m^0.5.

Keywords: Unstabilised zirconia sinters, Monoclinic zirconia sinters, Two step sintering, Mechanical properties